Zero-shot classification (ZSC) is a machine learning technique that allows models to predict categories they have never encountered during training, making it a form of transfer learning. This approach is particularly useful in web scraping, where it can dynamically categorize data from evolving web content without needing extensive retraining. ZSC leverages pre-trained language models, often fine-tuned on tasks like Natural Language Inference (NLI), to assign labels by treating input text as a premise and candidate labels as hypotheses, choosing the label with the highest entailment score. Its advantages include adaptability to new classes and reduced dependency on labeled data, though it may have limitations like performance variability and reliance on model quality. In web scraping, ZSC facilitates dynamic content categorization, sentiment analysis of new subjects, and the identification of trends, all without the necessity for retraining specific models for new data. The guide provides a detailed tutorial on implementing ZSC in a web scraping context, using the DistilBart-MNLI model from Hugging Face, showing how to extract and classify data from a target website.