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To integrate Twilio Messaging's SMS service with a Windows Presentation Foundation (WPF) application, developers can follow this tutorial. The WPF app will receive and send SMS messages using the Twilio helper library for .NET. A Twilio phone number is created to send and receive SMS messages programmatically through a Twilio phone number. The application architecture includes a user interface component, MainWindow.xaml, and a C# class that provides other functionality, MessageSender.cs. The project uses .NET Core SDK 3.1 and Visual Studio 2019 with the necessary workloads and individual components. To connect to Twilio, ngrok is used to create a secure and stable tunnel from the internet to the application's endpoints. The app will start listening on port 1337 in the self-host, and the Twilio service webhooks will call this endpoint when an SMS message arrives. The application uses ServiceStack for inversion of control and dependency injection. When the app is running, users can send and receive SMS messages using their mobile phone or computer.